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Thermal expansion occurs because increased temperature increases atomic vibrations, pushing atoms apart. Three types: linear (), area (, ), and volume (, ). The ratio is fundamental.
Key materials: Invar ( K) for precision instruments, Pyrex glass () for thermal shock resistance, steel () as a reference standard. Holes and cavities expand as if filled with the same material — a heated ring has a larger inner diameter.
Water exhibits anomalous expansion between 0 and 4 degrees C — it contracts on heating, reaching maximum density at 4 degrees C. This causes lakes to freeze from the top, with the bottom at 4 degrees C supporting aquatic life.
Bimetallic strips exploit differential expansion — two metals bonded together bend toward the less-expanding metal, used in thermostats. When expansion is constrained, thermal stress develops, independent of length.