- An ore is a mineral from which a metal can be economically extracted, whereas a mineral is merely any naturally occurring inorganic compound of a metal.
- Ores are classified as oxide, sulphide, carbonate, or halide based on the anion of the metal compound, with key examples including haematite (), zinc blende (ZnS), and cryolite ().
- Concentration removes gangue using hydraulic washing for heavy oxide ores, magnetic separation for magnetic ores, froth flotation for sulphide ores, and leaching for gold and aluminium.
- In froth flotation, pine oil is the collector that makes sulphide particles hydrophobic; NaCN acts as a depressant for ZnS, suppressing it so only PbS floats.
- Calcination heats carbonate or hydrated ores in limited air to give metal oxide and /, while roasting heats sulphide ores in excess air to give metal oxide and .
- The Ellingham diagram plots ° of oxide formation versus temperature; a metal whose oxide line is lower can reduce the oxide of a metal whose line is higher.
- The 2C + → 2CO line slopes downward because is positive, making carbon a progressively stronger reducing agent at higher temperatures — the basis of blast furnace smelting.
- Aluminium is extracted by the Hall-Heroult process: dissolved in molten cryolite at ~950 °C is electrolysed, depositing Al at the cathode while carbon anodes are consumed.
- Copper undergoes self-reduction in the Bessemer converter ( reduces to blister copper) and is then purified by electrolytic refining, with Au and Ag collecting in the anode mud.
- Specialised refining methods are required for specific metals: zone refining for Si/Ge, the Mond carbonyl process for Ni, and the Van Arkel iodide method for Ti and Zr.
Part of INC-06 — General Principles & Processes of Isolation of Elements
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