Part of PC-06 — Equilibrium: Chemical & Ionic

PC-06 — Visual Summary with Tables, Diagrams, and SMILES

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Le Chatelier Quick Reference Table

StressEquilibrium ShiftK Changes?
Add reactantForwardNo
Add productBackwardNo
Increase pressureToward fewer gas molesNo
Decrease pressureToward more gas molesNo
Increase temperatureToward endothermic directionYes (increases for endo, decreases for exo)
Add catalystNo shiftNo
Inert gas (const. V)No shiftNo
Inert gas (const. P)Toward more gas molesNo

Process Flow: Q vs K Decision

Solubility Product Summary

SaltFormulaKsp Expressions in Pure Water
AgClAg+Ag^{+} + ClCl^{-}[Ag+Ag^{+}][ClCl^{-}] = s2s^{2}s = √Ksp = 1.34×1051.34 \times 10^{-5} M
Ag2CrO4Ag_{2}CrO_{4}2Ag+Ag^{+} + CrO42CrO_{4}^{2-}[Ag+Ag^{+}]^{2}[CrO42CrO_{4}^{2-}] = 4s3s^{3}s = (Ksp/4)^(1/3)
BaSO4BaSO_{4}Ba2+Ba^{2+} + SO42SO_{4}^{2-}[Ba2+Ba^{2+}][SO42SO_{4}^{2-}] = s2s^{2}s = √Ksp
Ca(OH)_{2}Ca2+Ca^{2+} + 2OHOH^{-}[Ca2+Ca^{2+}][OHOH^{-}]^{2} = 4s3s^{3}s = (Ksp/4)^(1/3)

SMILES Representations of Key Species

  • Acetic acid (buffer): SMILES: CC(=O)O (ethanoic acid / acetic acid)
  • Acetate ion (conjugate base): SMILES: CC(=O)[O-] (acetate ion)
  • Ammonium ion (conjugate acid): SMILES: [NH4+] (ammonium ion)
  • Ammonia (weak base): SMILES: N (ammonia / $NH_{3}$)

pH Scale Visual

  0    1    2    3    4    5    6    7    8    9   10   11   12   13   14
  |────|────|────|────|────|────|────|────|────|────|────|────|────|────|
  ◄──────────── ACIDIC ────────────► N ◄──────────── BASIC ────────────►
  HCl                        $CH_{3}COOH$   NaCl        $NH_{3}$          NaOH
  (0.1M pH=1)              (0.1M≈2.9) (pH=7)   (0.1M pH≈11)  (0.1M pH=13)

Acid-Base Theory Comparison

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