- Electromagnetic radiation follows E = hν = hc/λ with c = m/s and h = J·s.
- In the photoelectric effect, electrons are ejected only when ν ≥ ν_{0}; kinetic energy KE = h(ν − ν_{0}) depends on frequency alone, not intensity.
- The hydrogen spectrum is described by the Rydberg formula: 1/λ = R_H(1/n_{1}^{2} − 1/n_{2}^{2}), with only the Balmer series (n_{1}=2) visible to the naked eye.
- Bohr's model gives E_n = −13.6/ eV, r_n = 0.529/Z Å, and v_n = Z/n m/s for hydrogen-like atoms.
- Total spectral lines when electrons de-excite from level n = n(n−1)/2 (not which counts orbitals).
- de Broglie wavelength λ = h/mv applies to all matter; the standing wave condition nλ = 2πr justifies Bohr's angular momentum quantization.
- The Heisenberg uncertainty principle (· ≥ h/4π) makes simultaneous exact knowledge of position and momentum impossible, invalidating Bohr's definite orbits.
- Four quantum numbers describe each electron: n (shell), l (shape, 0 to n−1), mₗ (orientation, −l to +l), mₛ (spin, ±½); nodes: total=n−1, angular=l, radial=n−l−1.
- Aufbau (n+l rule), Pauli (max 2 per orbital), and Hund's (maximum unpaired) govern electron filling; Cr=[Ar]34 and Cu=[Ar]34 are anomalous due to half/full d stability.
- For transition metal cations, 4s electrons are removed before 3d electrons (e.g., = [Ar]3 after removing 4 and one 3d from Fe).
Part of PC-02 — Atomic Structure
Overview Summary: 10-Sentence Condensed
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