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Part of PP-01 — Photosynthesis

Overview — 10-Sentence Summary

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Photosynthesis converts light energy to chemical energy (glucose) in plants, algae, and cyanobacteria, using $6CO_{2} + \12H_{2}O (\12H_{2}O confirmed by Van Niel) to produce glucose + \6O_{2} + \6H_{2}O. It occurs in chloroplasts: light reactions on thylakoid membranes (grana) and the Calvin cycle in the stroma. Chlorophyll a is the primary pigment with reaction centres P680 (PS II) and P700 (PS I); accessory pigments broaden the spectrum and transfer energy to Chl a. PS II (P680) acts first, splitting water (Hill reaction: \2H_{2}O4 → 4H^{+}+4 + 4e^{-}++O_{2})andinitiatingtheZschemeelectrontransportchain.Noncyclicphotophosphorylation(bothPSIandPSII)producesATP,NADPH,and) and initiating the Z-scheme electron transport chain. Non-cyclic photophosphorylation (both PS I and PS II) produces ATP, NADPH, and O_{2};cyclicphotophosphorylation(PSIonly,instromalamellae)producesATPonly.ATPsynthesisoccursbychemiosmosisthrough; cyclic photophosphorylation (PS I only, in stroma lamellae) produces ATP only. ATP synthesis occurs by chemiosmosis through CF_{0}-CF_{1},drivenbythe, driven by the H^{+}gradientbetweenthethylakoidlumenandstroma.TheCalvincycle(CRR)uses18ATPand12NADPHtofix6C gradient between the thylakoid lumen and stroma. The Calvin cycle (CRR) uses 18 ATP and 12 NADPH to fix 6 CO_{2}(viaRuBisCO+RuBP)intooneglucose,throughcarboxylation(3PGA),reduction(G3P),andregeneration(RuBP)stages.C4plants(maize,sugarcane)useKranzanatomyandPEPcarboxylasetofixC (via RuBisCO + RuBP) into one glucose, through carboxylation (→3-PGA), reduction (→G3P), and regeneration (→RuBP) stages. C4 plants (maize, sugarcane) use Kranz anatomy and PEP carboxylase to fix CO_{2}spatially(mesophyllbundlesheath),eliminatingphotorespiration;CAMplants(cacti,Bryophyllum)usetemporalseparation(nightC spatially (mesophyll → bundle sheath), eliminating photorespiration; CAM plants (cacti, Bryophyllum) use temporal separation (night CO_{2}fixation,dayCalvincycle).PhotorespirationisRuBisCOswastefuloxygenaseactivity,producingphosphoglycolateandconsumingATPwithoutgain,absentinC4/CAMplants.Blackmanslawstatesthatphotosynthesisrateislimitedbytheleastavailablefactorlightintensity,C fixation, day Calvin cycle). Photorespiration is RuBisCO's wasteful oxygenase activity, producing phosphoglycolate and consuming ATP without gain, absent in C4/CAM plants. Blackman's law states that photosynthesis rate is limited by the least available factor — light intensity, CO_{2}$ concentration, or temperature.

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