- Carbocation stability: 3° > 2° > 1° > — stabilized by +I effect and hyperconjugation from alkyl groups.
- Carbanion stability is the OPPOSITE: > 1° > 2° > 3° — alkyl +I effect destabilizes the negative carbon.
- Hyperconjugation = number of alpha C-H bonds — count them directly for the number of hyperconjugative structures.
- -OH is -I (sigma) but +M (pi) — in aromatic systems +M dominates, making -OH ortho/para-directing.
- Geometrical isomerism needs TWO conditions: restricted rotation (C=C or ring) AND different substituents on each doubly-bonded carbon — if either is missing, no E/Z isomerism exists.
Part of OC-01 — General Organic Chemistry Fundamentals
OC-01 Five Must-Know Facts for NEET
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