Part of JME-10 — Thermal Properties: Expansion, Calorimetry & Heat Transfer

Newton's Law of Cooling

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Newton's law: the rate of cooling is proportional to the temperature excess above surroundings: dT/dt=k(TTs)dT/dt = -k(T - T_s). Solution: T(t)=Ts+(T0Ts)ektT(t) = T_s + (T_0 - T_s)e^{-kt} (exponential approach to TsT_s).

For JEE, the practical average form is used: (T1T2)/t=k[(T1+T2)/2Ts](T_1 - T_2)/t = k \cdot [(T_1 + T_2)/2 - T_s]. This approximation works well when the temperature interval is not too large. Common problem type: given one cooling interval, find the time for the next. Two intervals can determine both kk and TsT_s (divide the two equations to eliminate kk).

The law is derived from Stefan's T4T^4 law by linearization: when TTsT \approx T_s, T4Ts44Ts3(TTs)T^4 - T_s^4 \approx 4T_s^3(T - T_s), giving the linear dependence. This is why Newton's law fails for large temperature differences (where the T4T^4 nonlinearity matters).

A cooling curve (T vs t) shows rapid initial cooling that gradually slows, asymptotically approaching TsT_s.

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