Part of JTHERM-02 — Kinetic Theory of Gases

Maxwell-Boltzmann Distribution

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The Maxwell-Boltzmann speed distribution f(v)=4πn(m/(2πkBT))3/2v2emv2/(2kBT)f(v) = 4\pi n(m/(2\pi k_BT))^{3/2} v^2 e^{-mv^2/(2k_BT)} gives the number of molecules with speeds between vv and v+dvv + dv. The distribution has three key features: (1) rises as v2v^2 at low speeds (phase space factor), (2) decays exponentially at high speeds (Boltzmann factor), and (3) peaks at vmp=2kBT/mv_{\text{mp}} = \sqrt{2k_BT/m}.

As temperature increases: the peak shifts right (higher vmpv_{\text{mp}}), the distribution broadens, and the peak height decreases (area under curve is conserved = total NN). As molecular mass increases: the peak shifts left and narrows (heavier molecules are slower and more uniform).

The distribution is not symmetric — it has a long tail at high speeds, which is why vavg>vmpv_{\text{avg}} > v_{\text{mp}} and vrms>vavgv_{\text{rms}} > v_{\text{avg}}. About 37% of molecules exceed vrmsv_{\text{rms}}, and a small but significant fraction have speeds far exceeding vmpv_{\text{mp}}.

For JEE, the qualitative shape and how it changes with TT and MM are more important than the formula itself. Know the ordering vmp<vavg<vrmsv_{\text{mp}} < v_{\text{avg}} < v_{\text{rms}} and the universal ratio.

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