Part of PC-02 — Atomic Structure

Key Points: All Formulas in LaTeX

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Electromagnetic Radiation: c=νλE=hν=hcλh=6.626×1034 J⋅sc = \nu\lambda \qquad E = h\nu = \frac{hc}{\lambda} \qquad h = 6.626 \times 10^{-34} \text{ J·s}

Photoelectric Effect: KEmax=hνhν0ϕ=hν0eV0=hνϕKE_{max} = h\nu - h\nu_0 \qquad \phi = h\nu_0 \qquad eV_0 = h\nu - \phi

Rydberg Formula: 1λ=RHZ2(1n121n22)RH=1.097×107 m1\frac{1}{\lambda} = R_H Z^2\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right) \qquad R_H = 1.097 \times 10^7 \text{ m}^{-1}

Bohr Model: En=13.6Z2n2 eVrn=0.529n2Z A˚vn=2.18×106Zn m/sE_n = -\frac{13.6Z^2}{n^2} \text{ eV} \qquad r_n = \frac{0.529n^2}{Z} \text{ Å} \qquad v_n = \frac{2.18 \times 10^6 Z}{n} \text{ m/s} L=nh2πTnn3Z2ΔE=13.6Z2(1n121n22) eVL = \frac{nh}{2\pi} \qquad T_n \propto \frac{n^3}{Z^2} \qquad \Delta E = 13.6Z^2\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right) \text{ eV}

Spectral Lines: Lines=n(n1)2\text{Lines} = \frac{n(n-1)}{2}

de Broglie: λ=hmv=hpλ=h2mKE=h2meV\lambda = \frac{h}{mv} = \frac{h}{p} \qquad \lambda = \frac{h}{\sqrt{2mKE}} = \frac{h}{\sqrt{2meV}}

Heisenberg Uncertainty: ΔxΔph4πΔxΔvh4πmΔEΔth4π\Delta x \cdot \Delta p \geq \frac{h}{4\pi} \qquad \Delta x \cdot \Delta v \geq \frac{h}{4\pi m} \qquad \Delta E \cdot \Delta t \geq \frac{h}{4\pi}

Quantum Numbers: l=0,1,2,,(n1)ml=l,,0,,+lms=±12l = 0, 1, 2, \ldots, (n-1) \qquad m_l = -l, \ldots, 0, \ldots, +l \qquad m_s = \pm\frac{1}{2} Orbitals per subshell=2l+1Electrons per subshell=2(2l+1)Electrons per shell=2n2\text{Orbitals per subshell} = 2l+1 \qquad \text{Electrons per subshell} = 2(2l+1) \qquad \text{Electrons per shell} = 2n^2

Nodes: Total=n1Angular=lRadial=nl1\text{Total} = n-1 \qquad \text{Angular} = l \qquad \text{Radial} = n-l-1

Virial Theorem: KE=EtotalPE=2Etotalhc=1240 eV⋅nm (shortcut)KE = -E_{total} \qquad PE = 2E_{total} \qquad hc = 1240 \text{ eV·nm (shortcut)}

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