Part of PC-09 — States of Matter

Key Points

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  • Ideal gas equation: PV=nRTPV = nRT; R=0.0821R = 0.0821 L·atm/(mol·K); always use Kelvin
  • Graham's law: r1/r2=M2/M1r_1/r_2 = \sqrt{M_2/M_1}; lighter gas diffuses faster; never invert the ratio
  • Molecular speed order: vmp<vavg<vrmsv_{mp} < v_{avg} < v_{rms} (formulas: 2RT/M<8RT/πM<3RT/M\sqrt{2RT/M} < \sqrt{8RT/\pi M} < \sqrt{3RT/M})
  • Compressibility factor: Z<1Z < 1 → attraction dominates; Z>1Z > 1 → repulsion dominates; H2H_{2} and He always Z>1Z > 1
  • Liquid state with temperature: vapour pressure ↑, surface tension ↓, viscosity ↓

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