Part of JINC-02 — d-Block & f-Block Elements

JEE Problem-Solving Strategy for d- and f-Block

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Electronic configuration (every year): Know anomalous configs of Cr and Cu. Remember: ions lose 4s first, then 3d. Practice writing configs for ions like Cr3+Cr^{3+}, Mn2+Mn^{2+}, Fe3+Fe^{3+}, Cu2+Cu^{2+}. Quick check: d-electron count = Z - 18 - charge (for 3d ions).

Oxidation state questions: Max OS = group number up to Mn(+7). Know stability patterns: d0d^0, d3d^3, d5d^5, d10d^{10} are extra stable. Higher OS with FF^-/O2O^{2-} (MnO4MnO4^-, CrO42CrO4^{2-}), lower OS with CO/CNCN^-.

KMnO4/K2Cr2O7 reactions: Know the half-reactions in all three media for KMnO4. Know the chromate-dichromate equilibrium direction with pH. Calculate n-factors: KMnO4 = 5(acid), 3(neutral), 1(alkaline); K2Cr2O7 = 6(acid).

Magnetic moment: Count unpaired electrons using d-configuration and ligand field. mu = sqrt(n(n+2)). Common values: d3d^3 = 3.87, d5d^5(HS) = 5.92, d8d^8 = 2.83 BM.

f-block: Focus on lanthanoid contraction (causes and consequences), anomalous oxidation states (Ce4+Ce^{4+} = 4f0f^0, Eu2+Eu^{2+} = 4f7f^7, Yb2+Yb^{2+} = 4f14f^{14}), and key differences between lanthanoids and actinoids.

Physical property trends: Know the anomalies — Mn (low m.p.), Cu (positive E degree), Zn (colourless, low m.p., d10d^{10}). These are the most tested exceptions to general trends.

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