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Electronic configuration (every year): Know anomalous configs of Cr and Cu. Remember: ions lose 4s first, then 3d. Practice writing configs for ions like , , , . Quick check: d-electron count = Z - 18 - charge (for 3d ions).
Oxidation state questions: Max OS = group number up to Mn(+7). Know stability patterns: , , , are extra stable. Higher OS with / (, ), lower OS with CO/.
KMnO4/K2Cr2O7 reactions: Know the half-reactions in all three media for KMnO4. Know the chromate-dichromate equilibrium direction with pH. Calculate n-factors: KMnO4 = 5(acid), 3(neutral), 1(alkaline); K2Cr2O7 = 6(acid).
Magnetic moment: Count unpaired electrons using d-configuration and ligand field. mu = sqrt(n(n+2)). Common values: = 3.87, (HS) = 5.92, = 2.83 BM.
f-block: Focus on lanthanoid contraction (causes and consequences), anomalous oxidation states ( = 4, = 4, = 4), and key differences between lanthanoids and actinoids.
Physical property trends: Know the anomalies — Mn (low m.p.), Cu (positive E degree), Zn (colourless, low m.p., ). These are the most tested exceptions to general trends.