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Step 1 — Identify the process: Look for keywords — "insulated" (adiabatic), "slowly" (quasi-static/isothermal if in thermal contact), "rigid container" (isochoric), "piston free to move" (often isobaric). If is given, it is polytropic.
Step 2 — Apply the First Law: . For ideal gases, always. Calculate using the process-specific formula. Find the third quantity.
Step 3 — Cyclic processes: (state function returns to start), so area enclosed on P-V diagram. Clockwise = positive work (engine), anticlockwise = negative work.
Step 4 — Carnot problems: Always convert to Kelvin first. Use . For combined engine-refrigerator problems, the work output of one drives the other.
Common traps: (1) Using Celsius in Carnot formula. (2) Confusing done "by" vs "on" the gas. (3) Applying only to isochoric — it works for all ideal gas processes. (4) Forgetting that free expansion has (no opposing pressure). (5) In mixing problems, use for gases in an insulated container.