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An isothermal process occurs at constant temperature (). For an ideal gas, this means , so the First Law simplifies to — all heat absorbed converts entirely to work (or vice versa). The equation of state gives Boyle's law: .
Work done in an isothermal process: . For expansion (), and the gas absorbs heat from the surroundings to maintain constant temperature. For compression, work is done on the gas and heat is released.
On a P-V diagram, an isothermal curve is a rectangular hyperbola (). The slope at any point is . An isothermal process requires two conditions: the system must be in thermal contact with a heat reservoir, and the process must be quasi-static (slow enough for temperature equilibrium at each step).
The specific heat during an isothermal process is effectively infinite: . This makes physical sense — you can add heat without changing temperature because it all converts to work.