Part of JTHERM-01 — Thermodynamics: Laws, Processes & Engines

Isothermal Process

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An isothermal process occurs at constant temperature (ΔT=0\Delta T = 0). For an ideal gas, this means ΔU=0\Delta U = 0, so the First Law simplifies to Q=WQ = W — all heat absorbed converts entirely to work (or vice versa). The equation of state gives Boyle's law: P1V1=P2V2P_1V_1 = P_2V_2.

Work done in an isothermal process: W=nRTln(V2/V1)=nRTln(P1/P2)W = nRT\ln(V_2/V_1) = nRT\ln(P_1/P_2). For expansion (V2>V1V_2 > V_1), W>0W > 0 and the gas absorbs heat from the surroundings to maintain constant temperature. For compression, work is done on the gas and heat is released.

On a P-V diagram, an isothermal curve is a rectangular hyperbola (PV=constantPV = \text{constant}). The slope at any point is dP/dV=P/VdP/dV = -P/V. An isothermal process requires two conditions: the system must be in thermal contact with a heat reservoir, and the process must be quasi-static (slow enough for temperature equilibrium at each step).

The specific heat during an isothermal process is effectively infinite: CT=Q/(nΔT)=Q/0C_T = Q/(n\Delta T) = Q/0 \to \infty. This makes physical sense — you can add heat without changing temperature because it all converts to work.

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