Part of JPH-02 — Atoms: Bohr Model & Hydrogen Spectrum

Hydrogen-like Ions and Scaling Laws

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Hydrogen-like ions (He+, Li2+, Be3+) have one electron and nuclear charge Z. All Bohr formulas apply with Z scaling: rnr_n = n2n^2a0a_0/Z (radius shrinks with Z), vnv_n = Zv0v_0/n (speed increases with Z), EnE_n = -13.6*Z2Z^2/n2n^2 eV (binding strengthens as Z2Z^2). For He+ (Z=2): ground state energy = -54.4 eV, ionization energy = 54.4 eV. For Li2+ (Z=3): ground state energy = -122.4 eV. Spectral wavelengths scale as 1/Z2Z^2 — all lines shift to shorter wavelengths for higher Z. A powerful JEE concept: certain transitions in different ions produce the same wavelength. For example, the 2 to 1 transition in He+ (Z=2) has 4 times the energy of 2 to 1 in H, giving lambda/4. The n=2 to n=1 transition in He+ has the same energy as n=4 to n=2 in H (both give 1/lambda = 3R). JEE frequently asks to match overlapping spectral lines between hydrogen and hydrogen-like ions.

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