The most frequently tested aspect of INC-03 in NEET is molecular geometry and hybridization. Here are the definitive key points:
Ozone (O3):
- Hybridization: sp2 | Geometry: Angular | Bond angle: ~117° | Lone pairs on central O: 1
SO2 vs. SO3 Comparison:
- SO2: sp2, angular (~119°), 1 lone pair on S, reducing agent
- SO3: sp2, trigonal planar (120°), 0 lone pairs on S, powerful oxidizer/acid anhydride
Xenon Fluorides — The Most Critical Table:
- XeF2: sp3d, linear (3 lone pairs equatorial in TBP, 2 F atoms axial, 180°)
- XeF4: sp3d2, square planar (2 lone pairs trans axial in octahedral, 4 F atoms equatorial)
- XeF6: sp3d3, distorted octahedral (1 lone pair distorts regular octahedral)
Interhalogen Geometries:
- AB (ClF): sp3 (diatomic, linear) — 3 lone pairs on central atom
- AB3 (ClF3): sp3d, T-shaped — 2 lone pairs equatorial in TBP
- AB5 (BrF5, IF5): sp3d2, square pyramidal — 1 lone pair in octahedral axial position
- AB7 (IF7): sp3d3, pentagonal bipyramidal — 0 lone pairs
VSEPR Lone Pair Rules:
- In trigonal bipyramidal (5 pairs): lone pairs prefer equatorial positions (120° vs. 90° repulsions)
- In octahedral (6 pairs): lone pairs prefer opposite (trans) positions (180° — maximum separation)
Hybridization Calculation Method:
- Hybridization = ½ [valence of central atom + bonds formed + charge adjustment]
- XeF2: ½[8 + 2] = 5 → sp3d
- XeF4: ½[8 + 4] = 6 → sp3d2
- XeF6: ½[8 + 6] = 7 → sp3d3
- ClF3: ½[7 + 3] = 5 → sp3d
- IF7: ½[7 + 7] = 7 → sp3d3
Common Geometry Traps:
- XeF2 looks like it should be bent (2 bonds) but is LINEAR (3 lone pairs in equatorial)
- XeF4 looks like it should be tetrahedral (4 bonds) but is SQUARE PLANAR (2 lone pairs)
- ClF3 might seem trigonal planar but is T-SHAPED (2 lone pairs occupy equatorial positions)