Part of JPH-01 — Modern Physics: Photoelectric Effect & Matter Waves

de Broglie Hypothesis and Matter Waves

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de Broglie (1924) proposed that every moving particle has wave nature with wavelength λ = hp\frac{h}{p} = hmv\frac{h}{mv}. For a particle with kinetic energy KE: λ = h/2mKE\sqrt{2mKE}. For a charged particle through potential V: λ = h/2mqV\sqrt{2mqV}. Quick formulas: electron λ = 12.27/√V Å, proton λ = 0.286/√V Å, alpha particle λ = 0.101/√V Å. Critical comparisons at the same KE: lighter particles have longer wavelengths (λ ∝ 1/√m). At the same momentum: all particles have the same wavelength. At the same speed: lighter particles have longer wavelengths (λ ∝ 1/m). Thermal de Broglie wavelength: λ = h/3mkT\sqrt{3mkT}. The connection to Bohr model: 2πr = nλ (standing wave condition gives angular momentum quantization). Davisson-Germer experiment (1927) confirmed the hypothesis by observing electron diffraction from nickel crystal at 54 V (λ_measured = 1.65 Å ≈ λ_predicted = 1.67 Å).

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