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de Broglie (1924) proposed that every moving particle has wave nature with wavelength λ = = . For a particle with kinetic energy KE: λ = h/. For a charged particle through potential V: λ = h/. Quick formulas: electron λ = 12.27/√V Å, proton λ = 0.286/√V Å, alpha particle λ = 0.101/√V Å. Critical comparisons at the same KE: lighter particles have longer wavelengths (λ ∝ 1/√m). At the same momentum: all particles have the same wavelength. At the same speed: lighter particles have longer wavelengths (λ ∝ 1/m). Thermal de Broglie wavelength: λ = h/. The connection to Bohr model: 2πr = nλ (standing wave condition gives angular momentum quantization). Davisson-Germer experiment (1927) confirmed the hypothesis by observing electron diffraction from nickel crystal at 54 V (λ_measured = 1.65 Å ≈ λ_predicted = 1.67 Å).