Part of INC-06 — General Principles & Processes of Isolation of Elements

Common Mistakes to Avoid in INC-06

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  • Confusing calcination and roasting: Calcination uses limited/absent air (for carbonates/hydrated ores); roasting uses excess air (for sulphide ores). Both produce metal oxides but by different conditions. The most common NEET trap is applying calcination to sulphide ores — wrong.
  • Misidentifying the Ellingham diagram direction: The 2C + O2O_{2} → 2CO line slopes downward (more negative ΔG\Delta G°) with temperature. Students often write it slopes upward. The C + O2O_{2} → CO2O_{2} line is nearly flat.
  • Thinking the lower Ellingham line is less stable: Lower line = more negative ΔG\Delta G° = more stable oxide = that metal does NOT get reduced easily. Confusing stability direction is a frequent error.
  • Mixing up anode and cathode in electrolytic refining: Impure metal is the anode (dissolves); pure metal is the cathode (deposits). Anode mud collects less electropositive metals (Au, Ag).
  • Forgetting that carbon anodes are consumed in Hall-Heroult: O2O^{2-} reacts with carbon at the anode forming CO2O_{2}. This is regularly tested.
  • Confusing Mond process temperatures: Formation of Ni(CO)_{4} at lower temperature (330–350 K); decomposition at higher temperature (450–470 K). Students swap these.
  • Assuming all minerals are ores: An ore must be economically extractable. Bauxite is an ore of Al; but AlCl3AlCl_{3} found in minute traces is just a mineral.
  • NaCN role confusion: NaCN is a depressant (suppresses ZnS), not a collector. Pine oil is the collector. Do not interchange these roles.
  • Blister copper purity: Blister copper is ~98% pure, not 100%. It requires further electrolytic refining to reach electrical grade.
  • Van Arkel vs Mond: Van Arkel uses iodide (Ti, Zr); Mond uses carbonyl (Ni). Do not mix the two processes or the metals.

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