Part of JPC-10 — Surface Chemistry & States of Matter

Colloidal Properties

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Tyndall effect: light scattering by particles (1-1000 nm range). Blue sky = Tyndall scattering by atmospheric particles. Brownian motion: random zig-zag movement due to unequal molecular bombardment. Stabilises colloid by preventing settling. Electrophoresis: migration of charged particles to oppositely charged electrode. Cataphoresis (particles to cathode = positive colloid). Anaphoresis (to anode = negative colloid). Electroosmosis: movement of dispersion medium under electric field. Coagulation: neutralisation of charge by electrolyte. Hardy-Schulze: coagulating power proportional to valence of oppositely charged ion. Negative colloids (As2S3, Au, Ag, starch, clay): coagulated by cations: Al3+Al^{3+} > Mg2+Mg^{2+} > Na+. Positive colloids (Fe(OH)3, Al(OH)3): coagulated by anions: PO43PO4^{3-} > SO42SO4^{2-} > Cl-. Gold number: mg of protective colloid (lyophilic) needed to prevent coagulation of 10 mL gold sol by 1 mL of 10% NaCl. Lower gold number = better protective action. Gelatin (0.005-0.01) > albumin > starch > gum arabic.

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