Part of JPH-02 — Atoms: Bohr Model & Hydrogen Spectrum

Bohr's Three Postulates

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Bohr (1913) resolved Rutherford's stability problem with three revolutionary postulates. First, electrons orbit the nucleus in specific allowed circular orbits called stationary states without radiating energy — this directly contradicts classical electrodynamics. Second, the angular momentum is quantized: L = mvr = nh2pi\frac{nh}{2pi} = n-hbar, where n = 1, 2, 3, ... This is equivalent to saying the electron's de Broglie wave forms a standing wave around the orbit (2pir = nlambda). Third, when an electron jumps between orbits, a photon is emitted or absorbed with frequency f = EiEfh\frac{E_i - E_f}{h}. The model successfully predicts hydrogen's spectrum with remarkable accuracy. It works for any hydrogen-like ion (one electron: He+, Li2+, Be3+) by including the nuclear charge Z. However, it fails completely for multi-electron atoms because it ignores electron-electron repulsion, cannot explain fine structure or transition intensities, and violates the uncertainty principle by assuming definite orbits.

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