Part of PC-02 — Atomic Structure

Worked Problem: Step-by-Step Calculations

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Problem 1: First Balmer Line Wavelength

Given: Electron transitions from n=3 to n=2 in hydrogen Find: Wavelength

Step 1: Identify the formula: 1λ=RH(1n121n22)\frac{1}{\lambda} = R_H\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)

Step 2: Substitute values: 1λ=1.097×107(1419)\frac{1}{\lambda} = 1.097 \times 10^7 \left(\frac{1}{4} - \frac{1}{9}\right)

Step 3: Compute bracket: 1419=9436=536\frac{1}{4} - \frac{1}{9} = \frac{9-4}{36} = \frac{5}{36}

Step 4: Multiply: 1λ=1.097×107×536=1.524×106 m1\frac{1}{\lambda} = 1.097 \times 10^7 \times \frac{5}{36} = 1.524 \times 10^6 \text{ m}^{-1}

Step 5: Invert: λ=11.524×106=6.56×107 m=656 nm (red)\lambda = \frac{1}{1.524 \times 10^6} = 6.56 \times 10^{-7} \text{ m} = \boxed{656 \text{ nm (red)}}

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