| Year | Scientist | Contribution |
|---|---|---|
| 1803 | John Dalton | Atomic theory: matter = indivisible atoms |
| 1897 | J.J. Thomson | Discovery of electron; "plum pudding" model |
| 1900 | Max Planck | Energy quantization: E = hν; birth of quantum theory |
| 1905 | Albert Einstein | Photoelectric effect explained by photons; quantum of light |
| 1909 | Millikan | Oil-drop experiment: measured charge of electron |
| 1911 | Ernest Rutherford | Nuclear model: dense positive nucleus; electrons in large empty space |
| 1913 | Niels Bohr | Quantized orbits for hydrogen; E_n = −13.6/; spectral series explained |
| 1924 | Louis de Broglie | Wave nature of matter: λ = h/mv |
| 1925 | Wolfgang Pauli | Exclusion principle: no two electrons with same 4 quantum numbers |
| 1925 | Werner Heisenberg | Matrix mechanics; uncertainty principle: · ≥ h/4π |
| 1926 | Erwin Schrödinger | Wave equation: ψ describes electron probability; orbitals replace orbits |
| 1927 | Friedrich Hund | Hund's rule: maximum spin multiplicity in degenerate orbitals |
Evolution of the Nuclear Model: Thomson (uniform sphere) → Rutherford (nucleus + orbiting electrons) → Bohr (quantized orbits) → Quantum mechanical (orbitals/probability)