The Nernst equation relates cell potential to non-standard conditions: E = - ln(Q). At 25 degrees C (298 K), this simplifies to E = - log(Q). The variable n is the number of electrons transferred in the balanced cell reaction. Q is the reaction quotient with products over reactants. For a concentration cell (same electrodes, different concentrations), = 0, so E = -log(Q). The cell drives toward equalising concentrations. At equilibrium, E = 0, giving = log(K). This connects electrochemistry to equilibrium constants. Common error: using the wrong value of n or forgetting to balance the equation first.
Part of JPC-03 — Electrochemistry: Nernst, Conductance & Cells
The Nernst Equation — Derivation and Application
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