Part of PC-10 — Surface Chemistry

Table Note

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PhenomenonDefinitionCauseSignificance
Tyndall EffectLight scattering, path visibleParticle size comparable to light wavelengthDistinguishes colloid from true solution
Brownian MotionContinuous zig-zag particle movementUnequal molecular bombardmentKeeps particles suspended (kinetic stability)
ElectrophoresisParticle migration in electric fieldCharged particles move to opposite electrodeDemonstrates colloidal charge; used in purification
CoagulationSettling/aggregation of particlesCharge neutralization by electrolyte/electric fieldCan be deliberate (water treatment) or avoided (colloid stabilization)
Protective Colloid ActionLyophilic colloid prevents lyophobic coagulationAdsorption of lyophilic colloid on lyophobic particleUsed in photography, ice cream, pharmaceuticals
DialysisRemoval of small molecules via semi-permeable membraneDiffusion of small particles through membranePurification of colloids; kidney function (hemodialysis)

Preparation vs. Purification — Quick Reference:

StepMethods
PreparationChemical reduction (Au sol), Hydrolysis (Fe(OH)_{3}), Double decomposition (As2S3As_{2}S_{3}), Bredig's arc, Peptization
PurificationDialysis (slow), Electrodialysis (faster, for ions), Ultrafiltration (fastest, mechanical)

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