Part of JEXP-01 — Experimental Skills (JEE-specific 18 experiments)

Surface Tension — Capillary Rise Method

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  • Tags: surface-tension, capillary, meniscus
  • Difficulty: Moderate

Surface tension T causes liquid to rise in a narrow capillary tube. At equilibrium: upward surface tension force = weight of liquid column. T x 2pircos(theta) = rhogpir2r^2h, giving T = rhogrh2cos(theta\frac{h}{2*cos(theta}). For water-glass: theta ≈ 0 (complete wetting), so T = rhogr*h/2. Meniscus correction: the liquid above the flat surface forms a hemispherical meniscus of volume ≈ 23\frac{2}{3}pir3r^3. Corrected height: heffh_{eff} = h + r/3. Measure the capillary radius using a traveling microscope (view the bore end-on). Measure h as the difference between the meniscus top and the flat surface level. For mercury-glass: theta ≈ 140 degrees (obtuse), so the meniscus is convex and the mercury level depresses below the flat surface. Surface tension decreases with increasing temperature (molecular cohesion weakens).

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