Part of JPC-07 — Atomic Structure: Quantum Numbers & Electronic Config

Spectral Lines Calculation

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Total lines from level n to all lower levels: nn12\frac{n-1}{2}. Lines in a specific series (to level n1): n - n1. From n=4: total = 432\frac{3}{2} = 6 lines. Lyman: 4-1=3, Balmer: 4-2=2, Paschen: 4-3=1. Check: 3+2+1=6. Wavelength calculation: 1/lambda = RZ2RZ^2(1/n12n1^2 - 1/n22n2^2). Longest wavelength in series = smallest energy transition (n2 = n1+1). Shortest wavelength (series limit) = largest energy transition (n2 = infinity). For the Balmer series limit: 1/lambda = R14\frac{1}{4} => lambda = 4/R = 364.7 nm. First Balmer line (H-alpha): lambda = 656 nm. Energy gap decreases as n increases (levels get closer together).

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