Two cases: (a) Rate = k[A]^2 (single reactant): Integrated: 1/[A] = 1/[A]_0 + kt. Plot: 1/[A] vs t is linear with slope = +k. Half-life: /2 = — inversely proportional to initial concentration. (b) Rate = k[A][B] (two reactants, equal initial concentrations): same integrated form. For unequal concentrations: k = ())log((b(a-x))/(a(b-x))), where a = [A]_0, b = [B]_0, x = amount reacted. Second order reactions: /2 doubles when initial concentration is halved. This dependence of /2 on [A]_0 distinguishes second order from first order.
Part of JPC-06 — Chemical Kinetics: Rate Laws & Arrhenius Equation
Second Order Reactions
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