Part of JOC-01 — GOC: Hybridization, Isomerism & Effects (I, M, H, R)

Resonance — Rules and Energy

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Rules for valid resonance structures:

  1. Same atomic connectivity (only electrons move, not atoms)
  2. Same number of total electrons (paired + unpaired)
  3. Same charge distribution (total formal charge conserved)
  4. All atoms must obey octet rule (except for elements like B, empty d-orbitals for S, P)
  5. More covalent bonds = more stable contributing structure

Resonance energy: Difference between actual energy and energy of the most stable contributing structure. Benzene: ~150 kJ/mol resonance energy.

JEE tip: When comparing resonance structures, one with charge on more electronegative atom is more stable. Structures with separated charges are less stable than neutral ones.

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