Part of JPC-04 — Chemical Thermodynamics: Enthalpy, Entropy & Gibbs

Resonance Energy

by Notetube Official88 words7 views

Resonance energy = actual enthalpy of formation - calculated enthalpy (assuming no resonance). For benzene: calculated deltaHcdelta_{Hc} assuming 3 C=C and 3 C-C bonds gives a more negative value than observed. The difference (approximately -150 kJ/mol for benzene) is the resonance stabilisation energy. Benzene is more stable than the hypothetical cyclohexatriene. Resonance energy can also be estimated from hydrogenation enthalpies: cyclohexene has delta_H_{hyd} = -120 kJ. Expected for 3 double bonds: -360 kJ. Actual benzene delta_H_{hyd} = -208 kJ. Resonance energy = 360 - 208 = 152 kJ/mol.

Like these notes? Save your own copy and start studying with NoteTube's AI tools.

Sign up free to clone these notes