Part of JPC-01 — Chemical Bonding: VSEPR, VBT & MOT

Resonance and Bond Order Equalisation

by Notetube Official104 words4 views

Resonance averages bond character across equivalent positions. In CO32CO3^{2-}, three equivalent C-O bonds exist with bond order = 1double+2single3\frac{1 double + 2 single}{3} = 4/3 = 1.33. All three bonds have identical length (intermediate between C-O single and C=O double). In benzene, each C-C bond has order 1.5 (alternating single-double averages out). In NO3-, three equivalent N-O bonds with bond order 4/3. In SO42SO4^{2-}, if we consider expanded octet resonance structures, bond order of each S-O bond can be computed similarly. Resonance-stabilised structures are more stable than any individual Lewis structure and have lower energy. The more equivalent resonance structures, the greater the stabilisation.

Like these notes? Save your own copy and start studying with NoteTube's AI tools.

Sign up free to clone these notes