Resonance averages bond character across equivalent positions. In , three equivalent C-O bonds exist with bond order = = 4/3 = 1.33. All three bonds have identical length (intermediate between C-O single and C=O double). In benzene, each C-C bond has order 1.5 (alternating single-double averages out). In NO3-, three equivalent N-O bonds with bond order 4/3. In , if we consider expanded octet resonance structures, bond order of each S-O bond can be computed similarly. Resonance-stabilised structures are more stable than any individual Lewis structure and have lower energy. The more equivalent resonance structures, the greater the stabilisation.
Part of JPC-01 — Chemical Bonding: VSEPR, VBT & MOT
Resonance and Bond Order Equalisation
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