Part of OC-05 — Alcohols, Phenols & Ethers

PYQ Analysis — Previous Year Question Patterns

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Frequently Tested Concepts (NEET 2017–2024)

Year RangeConcept TestedQuestion TypeFrequency
Multiple yearsPCC vs KMnO4KMnO_{4} product from 1° alcoholProduct identification MCQVery High
Multiple yearsPhenol acidity ordering with substituentsArrange in order MCQHigh
Multiple yearsKolbe reaction product and positionNamed reaction product MCQHigh
Multiple yearsReimer-Tiemann intermediate (:CCl2CCl_{2})Mechanism MCQMedium
Multiple yearsWilliamson synthesis: correct halide choiceReagent selection MCQHigh
Multiple yearsLucas test result for alcohol typeObservation-based MCQMedium
Multiple yearsPhenol + Br2Br_{2}/H2OH_{2}O product (no catalyst)Product/condition MCQMedium

Sample PYQ-Style Questions

Q1. Which of the following reagents converts cyclohexanol to cyclohexanone? Answer: PCC or K2Cr2O7K_{2}Cr_{2}O_{7} (both convert 2° alcohol → ketone; KMnO4KMnO_{4} also works)

Q2. The product of Kolbe reaction of sodium phenoxide with CO2CO_{2} followed by acidification is: Answer: Salicylic acid (SMILES:OC(=O)c1ccccc1O)

Q3. Phenol reacts with bromine water to give a white precipitate. The product is: Answer: 2,4,6-tribromophenol

Strategy: For reagent questions, always ask: (a) Is it oxidation or reduction? (b) Is the reagent mild or strong? (c) What are the conditions (anhydrous? aqueous?)

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