Part of INC-04 — d-Block, f-Block Elements & Coordination Compounds

PYQ Analysis — Most Tested Concepts in INC-04

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NEET Previous Year Question Frequency Analysis (2015–2025):

TopicApproximate FrequencyLast AppearedKey Variant
CFT: predict diamagnetic/paramagnetic from ligand7–8 times2024Given formula, identify spin state and μ
KMnO4KMnO_{4} product in specific medium6–7 times2023Identify colour change and ee^{-} gained
IUPAC nomenclature of complex5–6 times2024Name the complex from formula
Isomerism type identification5–6 times2023Geometrical, optical, linkage, ionisation
Configuration anomaly (Cr/Cu)4–5 times2022Write correct configuration
Lanthanoid contraction and consequence3–4 times2023Why Zr/Hf are similar
Biological coordination compounds3–4 times2024Match metal to compound
Spectrochemical series order3 times2022Arrange ligands weak to strong
Denticity and ligand classification3 times2023Identify EDTA as hexadentate
VBT inner vs outer orbital2–3 times2021sp^{3}$$d^{2} vs d^{2}$$sp^{3} hybridisation

PYQ Trend: Highest yield combination question: A single MCQ often combines CFT (identify ligand from spectrochemical series) + magnetic moment calculation. Example: "Which of the following complexes is diamagnetic: [Ni(CO){4}], [NiCl4NiCl_{4}]^{2-}, [Ni(NH3NH_{3}){4}]^{2+}, [Ni(H2OH_{2}O)_{6}]^{2+}?"

Answer logic: Ni in [Ni(CO)_{4}] is Ni0Ni^{0} (d10d^{10}) → all paired → diamagnetic. CO is strong field but here Ni is d10d^{10} regardless. [NiCl4NiCl_{4}]^{2-} is Ni2+Ni^{2+} (d8d^{8}) with weak field ClCl^{-} → tetrahedral, high spin → 2 unpaired → paramagnetic.

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