Part of JME-10 — Thermal Properties: Expansion, Calorimetry & Heat Transfer

Principle of Calorimetry

by Notetube Official112 words4 views
  • id: JME-10-N08
  • title: Mixing Problems — Heat Exchange
  • tags: calorimetry, mixing, conservation

In an isolated system, total heat exchanged is zero: miciΔTi=0\sum m_i c_i \Delta T_i = 0, or equivalently, heat lost by hotter bodies = heat gained by colder bodies. The final equilibrium temperature:

Tf=m1c1T1+m2c2T2m1c1+m2c2T_f = \frac{m_1 c_1 T_1 + m_2 c_2 T_2}{m_1 c_1 + m_2 c_2}

This is the weighted average temperature. For same material (c1=c2c_1 = c_2): Tf=(m1T1+m2T2)/(m1+m2)T_f = (m_1 T_1 + m_2 T_2)/(m_1 + m_2). Critical step in problems: always check whether any phase change occurs before calculating. If the heat available is insufficient for complete phase change, the system stays at the phase-change temperature.

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