Pattern 1: Physisorption vs. Chemisorption Comparison (Most Frequent)
- Question style: "Which of the following is TRUE/FALSE about physisorption/chemisorption?"
- Most tested property: Temperature effect (1 question nearly every other year)
- Key fact tested: Physisorption decreases with T; chemisorption first increases then decreases
- Second most tested: Number of layers (physisorption = multilayer; chemisorption = monolayer)
- Third: Enthalpy values (physisorption 20–40; chemisorption 80–240 kJ/mol)
Pattern 2: Hardy-Schulze Rule for Coagulation (High Frequency)
- Question style: Given charged colloid + list of electrolytes → which has highest/lowest coagulating power?
- Strategy: Identify sol charge → identify opposite-charged ion in each electrolyte → rank by valency
- Common examples: (negative) → > > ; Fe(OH){3} (positive) → [Fe(CN){6}]^{4-} > >
Pattern 3: Gold Number and Protective Colloids (Medium Frequency)
- Question style: Given gold numbers → rank by protective power; or define gold number
- Key: Lower gold number = BETTER protective colloid = LESS mass needed
- Memorize: Gelatin (0.005) < Albumin (0.1) < Starch (25)
Pattern 4: Colloidal Properties — Tyndall, Brownian Motion (Medium)
- Question style: "What phenomenon explains [observation]?" — match phenomenon to observation
- Tyndall effect = light scattering by colloid
- Brownian motion = zig-zag movement due to molecular bombardment
- Electrophoresis = migration in electric field → shows charge
- Coagulation = neutralization of charge → settling
Pattern 5: Freundlich Isotherm Calculation (Low-Medium)
- Numerical: Given k and n, find x/m at given P
- Given two data points (P, x/m), find k and 1/n
- Key: Always use clean numbers (P = perfect cube or square for 1/n = 1/3 or 1/2)
Pattern 6: Emulsion Type Identification (Low)
- O/W: milk, vanishing cream, cod liver oil → mixes with water
- W/O: butter, cold cream → does not mix with water