Part of JPC-07 — Atomic Structure: Quantum Numbers & Electronic Config

Photoelectric Effect

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Einstein's explanation: light consists of photons with E = hv = hclambda\frac{hc}{lambda}. KEmaxKE_{max} = hv - phi, where phi = hv0hv_0 = work function (minimum energy to eject electron). Below threshold frequency v0v_0: no electrons ejected regardless of intensity. Above v0v_0: KE increases linearly with frequency. Number of electrons ejected per second proportional to intensity (number of photons), NOT frequency. Stopping potential V0V_0: eV0eV_0 = KEmaxKE_{max} = hv - phi. Plot KEmaxKE_{max} vs v: straight line, slope = h, x-intercept = v0v_0, y-intercept = -phi. This proved particle nature of light and gave experimental value of Planck's constant h = 6.626 x 10^-34 J.s.

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