Part of PH-03 — Semiconductors & Electronic Devices

n-type vs p-type vs Intrinsic — Comparison Note

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FeatureIntrinsicn-typep-type
CompositionPure Si or GeSi/Ge + pentavalent dopantSi/Ge + trivalent dopant
Dopant examplesNoneP, As, Sb (group 15)B, Al, Ga, In (group 13)
Dopant valence5 valence electrons3 valence electrons
Majority carriersEqual (ee^{-} = h+h^{+})ElectronsHoles
Minority carriersEqual (ee^{-} = h+h^{+})HolesElectrons
Carrier relationn_e = n_h = n_in_e >> n_hn_h >> n_e
Fermi levelMiddle of gapShifts toward conduction bandShifts toward valence band
Donor/Acceptor levelNoneDonor level (just below CB)Acceptor level (just above VB)
Net chargeNeutralNeutral (dopant adds proton too)Neutral (dopant removes proton)
Conductivity vs TIncreases with TIncreases with TIncreases with T
Mass action lawn_e × n_h = n_i2i^{2}n_e × n_h = n_i2i^{2}n_e × n_h = n_i2i^{2}
Typical conductivityLow (room temp)Higher than intrinsicHigher than intrinsic

Key insight for NEET: All three types are electrically neutral. The mass action law applies universally. Doping increases one carrier type while proportionally DECREASING the other (inverse relationship via n_i2i^{2}).

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