| Feature | Intrinsic | n-type | p-type |
|---|---|---|---|
| Composition | Pure Si or Ge | Si/Ge + pentavalent dopant | Si/Ge + trivalent dopant |
| Dopant examples | None | P, As, Sb (group 15) | B, Al, Ga, In (group 13) |
| Dopant valence | — | 5 valence electrons | 3 valence electrons |
| Majority carriers | Equal ( = ) | Electrons | Holes |
| Minority carriers | Equal ( = ) | Holes | Electrons |
| Carrier relation | n_e = n_h = n_i | n_e >> n_h | n_h >> n_e |
| Fermi level | Middle of gap | Shifts toward conduction band | Shifts toward valence band |
| Donor/Acceptor level | None | Donor level (just below CB) | Acceptor level (just above VB) |
| Net charge | Neutral | Neutral (dopant adds proton too) | Neutral (dopant removes proton) |
| Conductivity vs T | Increases with T | Increases with T | Increases with T |
| Mass action law | n_e × n_h = n_ | n_e × n_h = n_ | n_e × n_h = n_ |
| Typical conductivity | Low (room temp) | Higher than intrinsic | Higher than intrinsic |
Key insight for NEET: All three types are electrically neutral. The mass action law applies universally. Doping increases one carrier type while proportionally DECREASING the other (inverse relationship via n_).