Polynomials: LMVT always applies (continuous and differentiable everywhere). For degree n polynomial, f'(c) = [f(b)-f(a)]/(b-a) gives a degree n-1 equation in c, which always has a solution in (a,b).
Exponentials: f(x) = e^x on [0,1]. f'(c) = e^c = e-1. c = ln(e-1) ≈ 0.541.
Trigonometric: f(x) = sin x on [0, pi]. f'(c) = cos c = (0-0)/pi = 0. c = pi/2. The tangent at pi/2 is horizontal, parallel to the secant from (0,0) to (pi,0).
Logarithmic: f(x) = ln x on [1, e]. f'(c) = 1/c = (1-0)/(e-1). c = e-1 ≈ 1.718.