Mnemonic 1: Anode/Cathode Reactions
"AN OX RED CAT"
- ANode = OXidation (loss of electrons)
- REDuction = CAThode (gain of electrons)
- Works for BOTH galvanic and electrolytic cells — no exceptions!
Mnemonic 2: Galvanic vs Electrolytic Polarity
"GANE" — Galvanic Anode Negative; Electrolytic is opposite (anode = positive)
- In Galvanic cells: anode = negative (−), cathode = positive (+)
- In Electrolytic cells: anode = positive (+), cathode = negative (−)
- Just remember: Electrolytic is SWITCHED compared to Galvanic
Mnemonic 3: Electrochemical Series (Reduction Potentials, Most to Least Negative)
"Lovely Kings Never Argue; Zany Fools Hope Copper Saves All Gold Fluorine"
- Li, K, Na, Al; Zn, Fe, H(SHE), Cu, S(Ag), Au, F_{2}
- Left to right: reducing power decreases, oxidizing power increases
- "Z-F-H" is the crucial middle — Zn displaces Fe, Fe displaces H, but Cu cannot displace H
Mnemonic 4: Nernst Equation Number
"Oh-Five-Nine-Two" = 0.0592 (the constant at 25°C)
- Full equation: E = E° − (0.0592/n) log Q
- Think of it as a phone number fragment: 0592
Mnemonic 5: Faraday's Law Formula Check
"w = MIT over nF" (like Massachusetts Institute of Technology / n Faradays)
- w (grams) = M(g/mol) × I(A) × t(s) / [n × F(C/mol)]
- Units check: (g/mol × A × s) / (C/mol) = g/mol × C / (C/mol) = g ✓ [since A·s = C]
Mnemonic 6: O Oxidation Number Exceptions (3 cases)
"POS-SUP" for O exceptions:
- Peroxides: O = −1 (, , )
- Superoxides: O = −1/2 ()
- O: O = +2 (only fluoride of oxygen)
Mnemonic 7: F = 96500 C/mol
"9-6-5-0-0" → 96500 Coulombs per mole of electrons. Remember: Faraday constant = 96500 (round from 96485). This is charge of 1 mol electrons = Avogadro's number × charge per electron = × = 96352 C ≈ 96500 C.