Part of PC-07 — Redox Reactions & Electrochemistry

Mnemonics for Electrochemistry

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Mnemonic 1: Anode/Cathode Reactions

"AN OX RED CAT"

  • ANode = OXidation (loss of electrons)
  • REDuction = CAThode (gain of electrons)
  • Works for BOTH galvanic and electrolytic cells — no exceptions!

Mnemonic 2: Galvanic vs Electrolytic Polarity

"GANE"Galvanic Anode Negative; Electrolytic is opposite (anode = positive)

  • In Galvanic cells: anode = negative (−), cathode = positive (+)
  • In Electrolytic cells: anode = positive (+), cathode = negative (−)
  • Just remember: Electrolytic is SWITCHED compared to Galvanic

Mnemonic 3: Electrochemical Series (Reduction Potentials, Most to Least Negative)

"Lovely Kings Never Argue; Zany Fools Hope Copper Saves All Gold Fluorine"

  • Li, K, Na, Al; Zn, Fe, H(SHE), Cu, S(Ag), Au, F_{2}
  • Left to right: reducing power decreases, oxidizing power increases
  • "Z-F-H" is the crucial middle — Zn displaces Fe, Fe displaces H, but Cu cannot displace H

Mnemonic 4: Nernst Equation Number

"Oh-Five-Nine-Two" = 0.0592 (the constant at 25°C)

  • Full equation: E = E° − (0.0592/n) log Q
  • Think of it as a phone number fragment: 0592

Mnemonic 5: Faraday's Law Formula Check

"w = MIT over nF" (like Massachusetts Institute of Technology / n Faradays)

  • w (grams) = M(g/mol) × I(A) × t(s) / [n × F(C/mol)]
  • Units check: (g/mol × A × s) / (C/mol) = g/mol × C / (C/mol) = g ✓ [since A·s = C]

Mnemonic 6: O Oxidation Number Exceptions (3 cases)

"POS-SUP" for O exceptions:

  • Peroxides: O = −1 (H2O2H_{2}O_{2}, Na2O2Na_{2}O_{2}, BaO2BaO_{2})
  • Superoxides: O = −1/2 (KO2KO_{2})
  • OF2F_{2}: O = +2 (only fluoride of oxygen)

Mnemonic 7: F = 96500 C/mol

"9-6-5-0-0" → 96500 Coulombs per mole of electrons. Remember: Faraday constant = 96500 (round from 96485). This is charge of 1 mol electrons = Avogadro's number × charge per electron = 6.022×10236.022 \times 10^{23} × 1.6×10191.6 \times 10^{-19} = 96352 C ≈ 96500 C.

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