Part of PC-10 — Surface Chemistry

Mnemonic Verse Note

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Adsorption Hierarchy (particle size order): "True is tiny (less than one), Colloid's middle (one to thousand), Suspensions settle (more than one-thousand)"

  • True solution: < 1 nm
  • Colloid: 1–1000 nm
  • Suspension: > 1000 nm

Freundlich 1/n Rule: "Zero to one, the isotherm's done — beyond that range, use another name." 1/n must lie between 0 and 1 for the Freundlich isotherm to be valid.

Lyophilic Examples (SGPG): "Starch and Gelatin, Proteins and Gum — all love water, they're never numb." Starch, Gelatin, Proteins, Gum arabic = lyophilic (water-loving, stable, reversible)

Lyophobic Examples (GAF): "Gold, Arsenic sulfide, Fe(OH){3} — all hate water, unstable, see?" Gold sol, As2S3As_{2}S_{3} sol, Fe(OH){3} sol = lyophobic (water-hating, unstable, irreversible)

Industrial Catalysts: "Haber-Fe, Contact-V, Ostwald-Pt"

  • Haber (N2N_{2} + H2H_{2}NH3NH_{3}): Fe catalyst
  • Contact (SO2SO_{2}SO3SO_{3}): V2O5V_{2}O_{5} catalyst
  • Ostwald (NH3NH_{3} → NO): Pt catalyst

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