Part of PC-02 — Atomic Structure

Mnemonic Note: Memory Aids for PC-02

by Notetube Official292 words3 views

1. Spectral Series — "Lovely Ballerinas Perform Beautiful Pirouettes"

  • Lyman — UV (lowest n_{1}=1, highest energy)
  • Balmer — Visible (n_{1}=2; ONLY visible series)
  • Paschen — Infrared (n_{1}=3)
  • Brackett — Infrared (n_{1}=4)
  • Pfund — Far Infrared (n_{1}=5)
  • Region shortcut: "UV-V-I-I-I" (one visible, four UV/IR)

2. Quantum Number l Values

  • s = 0 (zero lobes extra; sphere)
  • p = 1 (1 node plane; dumbbell)
  • d = 2 (2 node planes; cloverleaf)
  • f = 3 (3 node planes; complex)
  • Memory: "SPDFs" — SubParts Describe Fancy shapes

3. Electron Capacity

  • s: 2 (2×1)
  • p: 6 (2×3)
  • d: 10 (2×5)
  • f: 14 (2×7)
  • Pattern: 2, 6, 10, 14 (increases by 4)

4. Anomalous Configurations

  • Cr — "Chromium Craves Chrome" (3d5d^{5} half, 4s1s^{1})
  • Cu — "Copper Cuts to Complete" (3d10d^{10} full, 4s1s^{1})
  • Both LOSE one 4s electron to fill/half-fill d

5. Aufbau Diagonal Rule (n+l rule)

  • 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p...
  • Remember: 4s fills BEFORE 3d; BUT 4s empties BEFORE 3d in cation formation

6. Node Formula — "TRAIN" (Total = n−1, Radial = nAIN)

  • Total = n − 1
  • Radial = n − l − 1 (= Total − Angular)
  • Angular = l
  • Image: total nodes = radial + angular
  • Note: angular = l always, radial = fill what remains

7. Key Constants to Memorize

  • h = 6.626×10346.626 \times 10^{-34} J·s
  • c = 3×1083 \times 10^{8} m/s
  • R_H = 1.097×1071.097 \times 10^{7} m1m^{-1}
  • mₑ = 9.1×10319.1 \times 10^{-31} kg
  • 1 eV = 1.6×1011.6 \times 10^{-1}^{9} J
  • hc = 1240 eV·nm (handy shortcut)

Like these notes? Save your own copy and start studying with NoteTube's AI tools.

Sign up free to clone these notes