1. Spectral Series — "Lovely Ballerinas Perform Beautiful Pirouettes"
- Lyman — UV (lowest n_{1}=1, highest energy)
- Balmer — Visible (n_{1}=2; ONLY visible series)
- Paschen — Infrared (n_{1}=3)
- Brackett — Infrared (n_{1}=4)
- Pfund — Far Infrared (n_{1}=5)
- Region shortcut: "UV-V-I-I-I" (one visible, four UV/IR)
2. Quantum Number l Values
- s = 0 (zero lobes extra; sphere)
- p = 1 (1 node plane; dumbbell)
- d = 2 (2 node planes; cloverleaf)
- f = 3 (3 node planes; complex)
- Memory: "SPDFs" — SubParts Describe Fancy shapes
3. Electron Capacity
- s: 2 (2×1)
- p: 6 (2×3)
- d: 10 (2×5)
- f: 14 (2×7)
- Pattern: 2, 6, 10, 14 (increases by 4)
4. Anomalous Configurations
- Cr — "Chromium Craves Chrome" (3 half, 4)
- Cu — "Copper Cuts to Complete" (3 full, 4)
- Both LOSE one 4s electron to fill/half-fill d
5. Aufbau Diagonal Rule (n+l rule)
- 1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p...
- Remember: 4s fills BEFORE 3d; BUT 4s empties BEFORE 3d in cation formation
6. Node Formula — "TRAIN" (Total = n−1, Radial = nAIN)
- Total = n − 1
- Radial = n − l − 1 (= Total − Angular)
- Angular = l
- Image: total nodes = radial + angular
- Note: angular = l always, radial = fill what remains
7. Key Constants to Memorize
- h = J·s
- c = m/s
- R_H =
- mₑ = kg
- 1 eV = ^{9} J
- hc = 1240 eV·nm (handy shortcut)