Part of OC-05 — Alcohols, Phenols & Ethers

Mnemonic Note — Memory Aids for OC-05

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Mnemonic 1 — Lucas Test "3-2-1 Countdown"

"Tertiary is Turbo-fast, Secondary is Slow, Primary says Pass"

  • 3° → Immediate (< 5 min) — Turbo
  • 2° → 5-20 minutes — Slow
  • 1° → No reaction at RT — Pass (skip)

Mnemonic 2 — PCC vs KMnO4KMnO_{4} "P = Partial, K = Kaput"

  • PCC = Partial oxidation (stops at aldehyde)
  • KMnO4MnO_{4} = Kaput (complete oxidation to carboxylic acid)

Mnemonic 3 — Named Reactions "K for Carboxyl, R for formaldehyde"

  • Kolbe → adds CO2CO_{2} group (Car-boxyl) → salicylic acid
  • Reimer-Tiemann → adds CHO group (foRmyl) via :CCl2CCl_{2} → salicylaldehyde
  • Both give the product at the ortho position

Mnemonic 4 — Williamson Synthesis "1° or NO"

  • 1° halide = YES (SN2 proceeds cleanly)
  • 2° halide = Maybe (some elimination)
  • 3° halide = NO (E2 elimination dominates — gives alkene, not ether)

Mnemonic 5 — Phenol Acidity "EWG Makes Acidic, EDG Makes Basic"

  • Electron-Withdrawing Groups (-NO2NO_{2}, -Cl) → more acidic (lower pKa)
  • Electron-Donating Groups (-CH3CH_{3}, -OCH3CH_{3}) → less acidic (higher pKa)

Mnemonic 6 — Reducing Agents "NaBH4NaBH_{4} is Naïve, LiAlH4LiAlH_{4} is Lion"

  • NaBH4NaBH_{4} (Naïve) — gentle, only reduces aldehydes and ketones
  • LiAlH4LiAlH_{4} (Lion) — aggressive, reduces everything including carboxylic acids, esters, and amides

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