Mnemonic 1 — Lucas Test "3-2-1 Countdown"
"Tertiary is Turbo-fast, Secondary is Slow, Primary says Pass"
- 3° → Immediate (< 5 min) — Turbo
- 2° → 5-20 minutes — Slow
- 1° → No reaction at RT — Pass (skip)
Mnemonic 2 — PCC vs "P = Partial, K = Kaput"
- PCC = Partial oxidation (stops at aldehyde)
- K = Kaput (complete oxidation to carboxylic acid)
Mnemonic 3 — Named Reactions "K for Carboxyl, R for formaldehyde"
- Kolbe → adds group (Car-boxyl) → salicylic acid
- Reimer-Tiemann → adds CHO group (foRmyl) via : → salicylaldehyde
- Both give the product at the ortho position
Mnemonic 4 — Williamson Synthesis "1° or NO"
- 1° halide = YES (SN2 proceeds cleanly)
- 2° halide = Maybe (some elimination)
- 3° halide = NO (E2 elimination dominates — gives alkene, not ether)
Mnemonic 5 — Phenol Acidity "EWG Makes Acidic, EDG Makes Basic"
- Electron-Withdrawing Groups (-, -Cl) → more acidic (lower pKa)
- Electron-Donating Groups (-, -O) → less acidic (higher pKa)
Mnemonic 6 — Reducing Agents " is Naïve, is Lion"
- (Naïve) — gentle, only reduces aldehydes and ketones
- (Lion) — aggressive, reduces everything including carboxylic acids, esters, and amides