Part of PC-06 — Equilibrium: Chemical & Ionic

Mnemonic Master — Memory Hooks for Equilibrium

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Mnemonic 1: "CITCK" — What changes K?

Only Temperature Changes K → Remember: Temperature is the Tyrant (controls K); everything else is a guest.

  • Concentration → shifts position, NOT K
  • Inert gas → no shift (const. V) or shifts position (const. P), NOT K
  • Pressure → shifts position, NOT K
  • Catalyst → nothing changes, NOT K

Mnemonic 2: "QFBEK" — Q Comparison Rule

  • Q < KForward (not enough products yet)
  • Q > KBackward (too many products)
  • Q = KEquilibrium (done)

Phrase: "Quite Formidable Balances Everything at K"

Mnemonic 3: "Salt pH — Weak Side Wins"

  • Strong + Strong → Neutral (pH = 7)
  • Weak acid + Strong base → Basic (weak acid "loses" → basic solution)
  • Strong acid + Weak base → Acidic (weak base "loses" → acidic solution)

Mnemonic 4: "HH — pH = pKa + log(Salt/Acid)" → "Salt Over Acid" = SOA

Henderson-Hasselbalch: pH = pKa + log(Salt/Acid) — SOA (like "sow the seed")

Mnemonic 5: Ksp Formula Pattern

  • 1:1 (AgCl) → Ksp = s2s^{2} → s = √Ksp
  • 1:2 (PbI2PbI_{2}, Ca(OH)_{2}) → Ksp = 4s3s^{3} → s = (Ksp/4)^(1/3)
  • 1:3 → Ksp = 27s4s^{4}

Memory: "One-One Square; One-Two Four-Cube; One-Three Twenty-Seven-Fourth"

Mnemonic 6: Acid-Base Theory Scope

"Arrhenius is Aqueous, Bronsted-Lowry is Broader, Lewis is Largest" — ABL (A < B < L in scope)

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