Part of PC-01 — Some Basic Concepts in Chemistry

Misconceptions

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#✗ Wrong Belief✓ Correct Understanding
1"1 mol always weighs 1 g"1 mol weighs molar mass grams. H2H_{2} = 2 g/mol; NaCl = 58.5 g/mol.
2"22.4 L is the volume of 1 mol of any gas at any temperature"22.4 L/mol applies only at STP (0 °C, 1 atm). At 25 °C it is ~24.5 L/mol.
3"The empirical formula always differs from the molecular formula"They can be identical — e.g., H2H_{2}O, CO2CO_{2}, NaCl all have empirical = molecular formula.
4"Limiting reagent is always the reactant present in smaller mass"Limiting reagent is determined by mole ratio relative to stoichiometry, not by mass alone.
5"Molarity and molality are the same at room temperature"They are different: M uses volume of solution; m uses mass of solvent. They are numerically similar only in very dilute aqueous solutions.
6"Normality is always twice the molarity"Normality = Molarity × n-factor. n-factor depends on the specific reaction — it is 1 for HCl, 2 for H_{2}$$SO_{4} in neutralisation, but different in other reactions.
7"Mole fraction can be greater than 1"Mole fraction is always between 0 and 1. Sum of mole fractions of all components = 1.
8"% composition and mole fraction are the same thing"% composition is by mass; mole fraction is by moles. Converting requires dividing by molar mass.
9"Avogadro's number is 6.023×10236.023 \times 10^{23}"The correct value is 6.022×10236.022 \times 10^{23} mol1mol^{-1} (CODATA 2018: 6.02214076×10236.02214076 \times 10^{23}).
10"When a question says 'at STP', you can use PV = nRT freely"Use PV = nRT only when T and P are explicitly given. At stated STP (0 °C, 1 atm), use 22.4 L/mol directly for speed.

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