| # | ✗ Wrong Belief | ✓ Correct Understanding |
|---|---|---|
| 1 | "1 mol always weighs 1 g" | 1 mol weighs molar mass grams. = 2 g/mol; NaCl = 58.5 g/mol. |
| 2 | "22.4 L is the volume of 1 mol of any gas at any temperature" | 22.4 L/mol applies only at STP (0 °C, 1 atm). At 25 °C it is ~24.5 L/mol. |
| 3 | "The empirical formula always differs from the molecular formula" | They can be identical — e.g., O, , NaCl all have empirical = molecular formula. |
| 4 | "Limiting reagent is always the reactant present in smaller mass" | Limiting reagent is determined by mole ratio relative to stoichiometry, not by mass alone. |
| 5 | "Molarity and molality are the same at room temperature" | They are different: M uses volume of solution; m uses mass of solvent. They are numerically similar only in very dilute aqueous solutions. |
| 6 | "Normality is always twice the molarity" | Normality = Molarity × n-factor. n-factor depends on the specific reaction — it is 1 for HCl, 2 for H_{2}$$SO_{4} in neutralisation, but different in other reactions. |
| 7 | "Mole fraction can be greater than 1" | Mole fraction is always between 0 and 1. Sum of mole fractions of all components = 1. |
| 8 | "% composition and mole fraction are the same thing" | % composition is by mass; mole fraction is by moles. Converting requires dividing by molar mass. |
| 9 | "Avogadro's number is " | The correct value is (CODATA 2018: ). |
| 10 | "When a question says 'at STP', you can use PV = nRT freely" | Use PV = nRT only when T and P are explicitly given. At stated STP (0 °C, 1 atm), use 22.4 L/mol directly for speed. |
Part of PC-01 — Some Basic Concepts in Chemistry
Misconceptions
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