PRACTICAL ORGANIC CHEMISTRY (OC-10)
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__________________________|___________________________
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ELEMENT DETECTION FUNCTIONAL GROUP KEY PREPARATIONS
(Lassaigne's Test) TESTS & TITRATIONS
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______|_______ ______|_______ ______|_______
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N test S test C=O Group Non-C=O Acetanilide KMnO4/
| | | | Synthesis Oxalic Acid
Prussian Purple ┌───────┐ Phenol | Titration
Blue (nitro- | | (FeCl3→ | |
(NaCN+ prusside) Aldeh- Ketone Violet) p-Nitro- Self-indicating
FeSO4/ yde | acetanilide 60-70°C
H2SO4) | | Amine Endpoint=
| Tollens 2,4-DNP (Carbyl- Iodoform Persistent Pink
N+S: (Ag (orange amine→ (CHI3)
NaSCN→ mirror) ppt) isocyanide)
FeCl3→
Blood Red
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Halogen test
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______|_______
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Cl Br I
AgCl AgBr AgI
White Pale Yellow
Soluble Yellow Insoluble
in NH3 Partial in NH3
Part of OC-10 — Practical Organic Chemistry
Mind Map — Practical Organic Chemistry Overview
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