SOLUTIONS & COLLIGATIVE PROPERTIES
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SOLUTION TYPES LAWS & PRINCIPLES COLLIGATIVE PROPERTIES
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Ideal Non-Ideal Henry's Raoult's 4 Properties Van't Hoff
| | Law Law | Factor
$\Delta H$=0,$\Delta V$=0 +/- Dev p=K_H·x P_A=x_A·P°_A | |
B+T, C6+C7 | | | VP, $\Delta Tb$, i>1 (diss.)
↓↑ Gas Ideal↔Non-ideal $\Delta Tf$, π i<1 (assoc.)
Azeotropes Solubility Positive/Neg | |
| | Deviation Formulas Degree α
Min.boil Max.boil | | |
EtOH+$H_{2}O$ $CHCl_{3}$+Ac K_H↑→x↓ iKbm, iKfm 1+(n-1)α
with T iCRT 1-α/2
Central Rule: ALL colligative properties depend on the number of particles → connect through i (van't Hoff factor).