Part of JTHERM-02 — Kinetic Theory of Gases

Maxwell-Boltzmann Speed Distribution

by Notetube Official105 words3 views
  • id: JTHERM-02-N07
  • title: Distribution of Molecular Speeds
  • tags: maxwell-boltzmann, distribution, speed

Not all molecules in a gas have the same speed. The Maxwell-Boltzmann distribution f(v)=4πn(m/2πkBT)3/2v2emv2/(2kBT)f(v) = 4\pi n(m/2\pi k_BT)^{3/2}v^2 e^{-mv^2/(2k_BT)} gives the number of molecules per unit speed interval. The distribution has key features: (1) starts at zero for v=0v = 0, (2) rises to a maximum at vpv_p, (3) falls exponentially at high speeds. At higher temperatures, the peak shifts right (higher vpv_p) and the curve broadens and flattens, but the total area under the curve (total number of molecules) remains constant. Heavier molecules have narrower distributions at the same temperature.

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