Part of JME-10 — Thermal Properties: Expansion, Calorimetry & Heat Transfer

Latent Heat and Phase Changes

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  • id: JME-10-N09
  • title: Latent Heat of Fusion and Vaporization
  • tags: latent-heat, fusion, vaporization, phase-change

During phase change, temperature remains constant while heat is absorbed/released: Q=mLQ = mL. Water's latent heats: Lf=3.34×105L_f = 3.34 \times 10^5 J/kg (80 cal/g) for fusion, Lv=2.26×106L_v = 2.26 \times 10^6 J/kg (540 cal/g) for vaporization. LvLfL_v \gg L_f because vaporization requires breaking all intermolecular bonds and doing work against atmospheric pressure. A heating curve (temperature vs heat) shows flat portions at phase transitions and rising portions between them. The slope of the rising portions is 1/(mc)1/(mc) — steeper for lower specific heat.

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