Part of JINC-02 — d-Block & f-Block Elements

Lanthanoid Series — General Properties

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Lanthanoids (La-Lu, Z=57-71) have general configuration [Xe]4f^(0-14) 5d^(0-1) 6s2s^2. Dominant oxidation state is +3 for all. They are silvery-white, soft metals that tarnish rapidly in air. All are paramagnetic except La3+La^{3+} (4f0f^0) and Lu3+Lu^{3+} (4f14f^{14}). Chemical properties are very similar (due to similar ionic radii from lanthanoid contraction), making separation extremely difficult — ion exchange chromatography is the modern method. Most form M2O3 oxides (basic), MCl3 chlorides, and M(OH)3 hydroxides. Basicity of hydroxides decreases from La(OH)3 to Lu(OH)3 as ionic radius decreases.

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