Lanthanoids (La-Lu, Z=57-71) have general configuration [Xe]4f^(0-14) 5d^(0-1) 6. Dominant oxidation state is +3 for all. They are silvery-white, soft metals that tarnish rapidly in air. All are paramagnetic except (4) and (4). Chemical properties are very similar (due to similar ionic radii from lanthanoid contraction), making separation extremely difficult — ion exchange chromatography is the modern method. Most form M2O3 oxides (basic), MCl3 chlorides, and M(OH)3 hydroxides. Basicity of hydroxides decreases from La(OH)3 to Lu(OH)3 as ionic radius decreases.
Part of JINC-02 — d-Block & f-Block Elements
Lanthanoid Series — General Properties
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