Part of JINC-02 — d-Block & f-Block Elements

Lanthanoid Contraction

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Definition: The steady decrease in atomic and ionic (M3+M^{3+}) radii across the lanthanoid series from La3+La^{3+} (106 pm) to Lu3+Lu^{3+} (85 pm). Cause: 4f electrons are poor shielders (diffuse, inner orbital), so each additional 4f electron does not fully shield the increasing nuclear charge → effective nuclear charge increases → contraction. Consequences: (1) Near-identical radii of 4d and 5d elements in same group (Zr/Hf: 160/159 pm, Nb/Ta: 146/146 pm). (2) Difficulty separating lanthanoids. (3) Decreasing basicity La(OH)3 > Lu(OH)3. (4) Complex formation tendency increases La3+La^{3+} < Lu3+Lu^{3+}. (5) Coordination numbers decrease slightly across the series.

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