Part of INC-04 — d-Block, f-Block Elements & Coordination Compounds

KMnO4 Reactions in Three Media — Process Flow

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Ionic Equations:

Acidic: MnO4+8H++5eMn2++4H2O\text{MnO}_4^- + 8\text{H}^+ + 5e^- \longrightarrow \text{Mn}^{2+} + 4\text{H}_2\text{O}

Neutral: MnO4+2H2O+3eMnO2+4OH\text{MnO}_4^- + 2\text{H}_2\text{O} + 3e^- \longrightarrow \text{MnO}_2 + 4\text{OH}^-

Basic: MnO4+eMnO42\text{MnO}_4^- + e^- \longrightarrow \text{MnO}_4^{2-}

Memory hook: Electrons gained go 5 → 3 → 1 as medium goes Acid → Neutral → Base. The colour sequence is Purple → Colourless / Brown / Green.

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