Part of JINC-04 — s-Block Elements & Hydrogen

Hydrogen — Position and Dual Nature

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Hydrogen (1s1s^1) does not fit neatly into any group. Similarities with Group 1: ns1ns^1 configuration, forms H+H^+ cation, electropositive. Similarities with Group 17: one electron short of noble gas configuration (1s2s^2), forms HH^- hydride ion, high IE (1312 kJ/mol, much higher than any alkali metal), forms diatomic H2 molecule like halogens. Placed in Group 1 by IUPAC convention, but its chemistry is largely covalent. H+H^+ (bare proton) never exists free in solution — always hydrated as H3O+H3O^+ (hydronium). Hydrogen has three isotopes: protium (^1H, 99.98%), deuterium (^2H or D, 0.02%), tritium (^3H or T, radioactive, beta emitter, t1/2 = 12.3 years).

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